| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Manuel Ugarte | Sporting CP | vs Arsenal | 118' | UEFA Europa League | 16 Mar 2023 |
| Jordi Alba | Barcelona | vs Espanyol | 78' | La Liga | 31 Dec 2022 |
| Vinicius Souza | Espanyol | vs Barcelona | 80' | La Liga | 31 Dec 2022 |
| Sergio Canales | Real Betis | vs Cádiz | 90' | La Liga | 19 Oct 2022 |
| James Sands | Rangers | vs Napoli | 55' | UEFA Champions League | 14 Sept 2022 |
| Tomás Alarcón | Cádiz | vs Osasuna | 76' | La Liga | 20 Aug 2022 |
| Franco Russo | Mallorca | vs Getafe | 63' | La Liga | 2 Apr 2022 |
| Thibaut Courtois | Atlético Madrid | vs Real Madrid | 22' | La Liga | 26 Nov 2011 |
| Diego Godín | Atlético Madrid | vs Real Madrid | 81' | La Liga | 26 Nov 2011 |
| Casto | Real Betis | vs Real Zaragoza | 69' | La Liga | 22 Sept 2011 |
| Iker Casillas | Real Madrid | vs Espanyol | 2' | La Liga | 13 Feb 2011 |
| Fernando Amorebieta | Athletic Club | vs Barcelona | 34' | La Liga | 25 Sept 2010 |
| David Villa | Barcelona | vs Athletic Club | 87' | La Liga | 25 Sept 2010 |