| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Edgar González | Real Betis | vs Barcelona | 33' | La Liga | 29 Apr 2023 |
| Abde Ezzalzouli | Osasuna | vs Cádiz | 85' | La Liga | 25 Apr 2023 |
| Ilaix Moriba | Valencia | vs Sevilla | 84' | La Liga | 16 Apr 2023 |
| José Ángel Carmona | Elche | vs Espanyol | 81' | La Liga | 19 Feb 2023 |
| Luiz Felipe | Real Betis | vs Celta Vigo | 90' | La Liga | 4 Feb 2023 |
| Santiago Bueno | Girona | vs Villarreal | 78' | La Liga | 22 Jan 2023 |
| Ivan Rakitić | Sevilla | vs Real Sociedad | 28' | La Liga | 9 Nov 2022 |
| Tanguy Nianzou | Sevilla | vs Real Sociedad | 34' | La Liga | 9 Nov 2022 |
| Gabri Veiga | Celta Vigo | vs Almería | 32' | La Liga | 29 Oct 2022 |
| Tuta | Eintracht Frankfurt | vs Tottenham Hotspur | 59' | UEFA Champions League | 12 Oct 2022 |
| Germán Pezzella | Real Betis | vs Real Valladolid | 35' | La Liga | 9 Oct 2022 |
| Maurizio Lanzaro | Real Zaragoza | vs Villarreal | 80' | La Liga | 1 Oct 2011 |