| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Adil Rami | Valencia | vs Málaga | 84' | La Liga | 24 Nov 2012 |
| Iñigo Martínez | Real Sociedad | vs Rayo Vallecano | 12' | La Liga | 6 Nov 2011 |
| Wilfredo Caballero | Málaga | vs Levante | 27' | La Liga | 16 Oct 2011 |
| Piotr Trochowski | Sevilla | vs Valencia | 56' | La Liga | 24 Sept 2011 |
| Julien Escudé | Sevilla | vs Valencia | 68' | La Liga | 24 Sept 2011 |
| Aritz Aduriz | Valencia | vs Sevilla | 71' | La Liga | 24 Sept 2011 |
| Martín Demichelis | Málaga | vs Athletic Club | 52' | La Liga | 15 May 2011 |
| Gary Medel | Sevilla | vs Osasuna | 90' | La Liga | 11 May 2011 |
| Ander Herrera | Real Zaragoza | vs Almería | 90' | La Liga | 25 Apr 2011 |
| Raúl Albiol | Real Madrid | vs Barcelona | 51' | La Liga | 16 Apr 2011 |
| Rubén | Mallorca | vs Getafe | 63' | La Liga | 5 Dec 2010 |
| Fernando Navarro | Sevilla | vs Real Zaragoza | 71' | La Liga | 14 Nov 2010 |
| David Trezeguet | Hercules | vs Villarreal | 44' | La Liga | 18 Oct 2010 |
| Borja Valero | Villarreal | vs Hercules | 81' | La Liga | 18 Oct 2010 |
| Mateo Musacchio | Villarreal | vs Hercules | 83' | La Liga | 18 Oct 2010 |
| José Antonio Reyes | Atlético Madrid | vs Real Zaragoza | 60' | La Liga | 26 Sept 2010 |
| Pedro Mosquera | Getafe | vs Deportivo La Coruña | 80' | La Liga | 20 Sept 2010 |