| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Asier Osambela | Osasuna | vs Alavés | 90' | La Liga | 5 Apr 2026 |
| Nobel Mendy | Rayo Vallecano | vs Levante | 53' | La Liga | 16 Mar 2026 |
| Joel Roca | Girona | vs Barcelona | 90' | La Liga | 16 Feb 2026 |
| Pedri | Barcelona | vs Real Madrid | 90' | La Liga | 26 Oct 2025 |
| Andriy Lunin | Real Madrid | vs Barcelona | 90' | La Liga | 26 Oct 2025 |
| Clément Lenglet | Atlético Madrid | vs Celta Vigo | 40' | La Liga | 5 Oct 2025 |
| Leandro Cabrera | Espanyol | vs Barcelona | 80' | La Liga | 15 May 2025 |
| Kylian Mbappé | Real Madrid | vs Alavés | 38' | La Liga | 13 Apr 2025 |
| Manu Sánchez | Alavés | vs Real Madrid | 70' | La Liga | 13 Apr 2025 |
| Stanko Juric | Real Valladolid | vs Athletic Club | 56' | La Liga | 23 Feb 2025 |
| Vinícius Júnior | Real Madrid | vs Valencia | 79' | La Liga | 3 Jan 2025 |
| Marc Casadó | Barcelona | vs Celta Vigo | 82' | La Liga | 23 Nov 2024 |
| Julen Agirrezabala | Athletic Club | vs Sevilla | 82' | La Liga | 29 Sept 2024 |
| Ferland Mendy | Real Madrid | vs Mallorca | 90' | La Liga | 18 Aug 2024 |
| Víctor Chust | Cádiz | vs Las Palmas | 74' | La Liga | 19 May 2024 |
| Santi Comesaña | Villarreal | vs Celta Vigo | 17' | La Liga | 5 May 2024 |
| Caglar Söyüncü | Atlético Madrid | vs Sevilla | 70' | La Liga | 23 Dec 2023 |
| Luca de la Torre | Celta Vigo | vs Alavés | 68' | La Liga | 28 Sept 2023 |
| Raphinha | Barcelona | vs Getafe | 42' | La Liga | 13 Aug 2023 |
| Jaime Mata | Getafe | vs Barcelona | 57' | La Liga | 13 Aug 2023 |
| Marcos Acuña | Sevilla | vs Real Madrid | 83' | La Liga | 27 May 2023 |
| Gabriel Paulista | Valencia | vs Celta Vigo | 90' | La Liga | 14 May 2023 |
| Edu Expósito | Espanyol | vs Villarreal | 90' | La Liga | 27 Apr 2023 |
| Pedro Bigas | Elche | vs Sevilla | 41' | La Liga | 28 Jan 2023 |
| Jordan Amavi | Getafe | vs Elche | 78' | La Liga | 31 Oct 2022 |
| Enrique Salas | Sevilla | vs Valencia | 90' | La Liga | 18 Oct 2022 |
| Luiz Felipe | Real Betis | vs Celta Vigo | 20' | La Liga | 2 Oct 2022 |