| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Karlen Mkrtchain | Anzhi Makhachkala | vs AZ Alkmaar | 90' | UEFA Europa League | 20 Mar 2014 |
| Joël Matip | Schalke 04 | vs FC Twente | 60' | UEFA Europa League | 8 Mar 2012 |
| Bashkim Kadrii | Odense BK | vs Villarreal | 71' | UEFA Champions League | 23 Aug 2011 |
| Borja Valero | Villarreal | vs Odense BK | 76' | UEFA Champions League | 23 Aug 2011 |
| Xabi Alonso | Real Madrid | vs Ajax Amsterdam | 87' | UEFA Champions League | 23 Nov 2010 |
| Sergio Ramos | Real Madrid | vs Ajax Amsterdam | 90' | UEFA Champions League | 23 Nov 2010 |