| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Gerard Piqué Bernabéu | Barcelona | vs Getafe | 24' | La Liga | 6 Feb 2010 |
| Rafael Márquez Álvarez | Barcelona | vs Getafe | 91' | La Liga | 6 Feb 2010 |
| Eric-Sylvain Bilal Abidal | Barcelona | vs Villarreal | 76' | La Liga | 10 May 2009 |
| Seydou Kéita | Sevilla | vs Barcelona | 77' | La Liga | 9 Feb 2008 |
| Anderson Luís de Souza | Barcelona | vs Athletic Club | 90' | La Liga | 15 Jan 2006 |