| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Jesús Gámez | Málaga | vs Osasuna | 52' | La Liga | 10 Mar 2014 |
| David Albelda | Valencia | vs Osasuna | 90' | La Liga | 22 Jan 2012 |
| Diego López | Villarreal | vs Sevilla | 22' | La Liga | 10 Sept 2011 |
| Xisco Nadal | Levante | vs Valencia | 21' | La Liga | 15 May 2011 |
| Luis Perea | Atlético Madrid | vs Athletic Club | 39' | La Liga | 30 Jan 2011 |
| Alexis | Sevilla | vs Almería | 89' | La Liga | 11 Dec 2010 |
| Leonardo Ponzio | Real Zaragoza | vs Getafe | 63' | La Liga | 22 Nov 2010 |