| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Brais Méndez | Real Sociedad | vs Athletic Club | 83' | La Liga | 1 Feb 2026 |
| Lucas Boyé | Alavés | vs Espanyol | 90' | La Liga | 2 Nov 2025 |
| Santiago Mouriño | Villarreal | vs Real Madrid | 77' | La Liga | 4 Oct 2025 |
| Ángel Correa | Atlético Madrid | vs Getafe | 88' | La Liga | 9 Mar 2025 |
| Marcos Alonso | Celta Vigo | vs Rayo Vallecano | 90' | La Liga | 10 Jan 2025 |
| Chimy Ávila | Real Betis | vs Villarreal | 34' | La Liga | 15 Dec 2024 |
| Jonathan Viera | Almería | vs Getafe | 90' | La Liga | 27 Apr 2024 |
| Santi Comesaña | Villarreal | vs Athletic Club | 46' | La Liga | 14 Apr 2024 |
| Nico Williams | Athletic Club | vs Real Betis | 40' | La Liga | 25 Feb 2024 |
| Suso | Sevilla | vs Osasuna | 86' | La Liga | 28 Jan 2024 |
| Gabriel Paulista | Valencia | vs Getafe | 50' | La Liga | 8 Dec 2023 |
| Javi Guerra | Valencia | vs Getafe | 88' | La Liga | 8 Dec 2023 |
| Domingos Duarte | Getafe | vs Valencia | 90' | La Liga | 8 Dec 2023 |
| Iván Villar | Celta Vigo | vs Atlético Madrid | 25' | La Liga | 21 Oct 2023 |
| Joseph Aidoo | Celta Vigo | vs Getafe | 77' | La Liga | 3 May 2023 |
| Sergio Canales | Real Betis | vs Cádiz | 38' | La Liga | 9 Apr 2023 |
| Aitor Ruibal | Real Betis | vs Cádiz | 60' | La Liga | 9 Apr 2023 |
| Pape Gueye | Sevilla | vs Atlético Madrid | 80' | La Liga | 4 Mar 2023 |
| Yeray | Athletic Club | vs Real Sociedad | 60' | La Liga | 14 Jan 2023 |
| Gonzalo Verdú | Elche | vs Atlético Madrid | 45' | La Liga | 29 Dec 2022 |
| Mario Hermoso | Atlético Madrid | vs Elche | 53' | La Liga | 29 Dec 2022 |
| Domingos Quina | Elche | vs Atlético Madrid | 90' | La Liga | 29 Dec 2022 |
| Gonçalo Paciência | Celta Vigo | vs Real Sociedad | 90' | La Liga | 16 Oct 2022 |
| David García | Osasuna | vs Real Madrid | 78' | La Liga | 2 Oct 2022 |
| Erik Lamela | Sevilla | vs Espanyol | 84' | La Liga | 10 Sept 2022 |
| John Donald | Elche | vs Real Betis | 16' | La Liga | 15 Aug 2022 |
| Gonzalo Escalante | Alavés | vs Levante | 90' | La Liga | 15 May 2022 |
| Ximo Navarro | Alavés | vs Celta Vigo | 64' | La Liga | 7 May 2022 |