| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Alejandro Pozuelo | Real Betis | vs Atlético Madrid | 72' | La Liga | 18 Dec 2011 |
| Eneko Satrustegui | Osasuna | vs Espanyol | 76' | La Liga | 27 Nov 2011 |
| Marius Stankevicius | Valencia | vs Real Zaragoza | 64' | La Liga | 12 Mar 2011 |
| Nacho Monreal | Osasuna | vs Atlético Madrid | 60' | La Liga | 13 Nov 2010 |
| Diego Colotto | Deportivo La Coruña | vs Almería | 42' | La Liga | 26 Sept 2010 |