| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Anderson Luis de Carvalho | Espanyol | vs Barcelona | 46' | La Liga | 27 Sept 2008 |
| Marco Materazzi | Italy | vs Australia | 51' | 2006 FIFA World Cup | 26 Jun 2006 |
| Radosław Sobolewski | Poland | vs Germany | 75' | 2006 FIFA World Cup | 14 Jun 2006 |