| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Pape Gueye | Villarreal | vs Athletic Club | 83' | La Liga | 6 Apr 2025 |
| Enrique García | Alavés | vs Real Valladolid | 90' | La Liga | 18 Oct 2024 |
| Álvaro García | Rayo Vallecano | vs Las Palmas | 81' | La Liga | 20 Jan 2024 |
| Florian Lejeune | Rayo Vallecano | vs Elche | 27' | La Liga | 29 Apr 2023 |
| Oihan Sancet | Athletic Club | vs Rayo Vallecano | 90' | La Liga | 5 Mar 2023 |
| Toni Kroos | Real Madrid | vs Girona | 90' | La Liga | 30 Oct 2022 |
| Benjamin Lecomte | Espanyol | vs Real Madrid | 90' | La Liga | 28 Aug 2022 |