| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Robin van Persie | Arsenal | vs Barcelona | 56' | UEFA Champions League | 8 Mar 2011 |
| Denys Garmash | Dynamo Kyiv | vs Ajax Amsterdam | 56' | UEFA Champions League | 17 Aug 2010 |
| Itumeleng Khune | South Africa | vs Uruguay | 76' | 2010 FIFA World Cup | 16 Jun 2010 |
| Vladyslav Vashchuk | Ukraine | vs Spain | 47' | 2006 FIFA World Cup | 14 Jun 2006 |