| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Abdel Abqar | Getafe | vs Atlético Madrid | 55' | La Liga | 14 Mar 2026 |
| Kervin Arriaga | Levante | vs Valencia | 90' | La Liga | 15 Feb 2026 |
| David Affengruber | Elche | vs Alavés | 79' | La Liga | 5 Oct 2025 |
| Dani Vivian | Athletic Club | vs Valencia | 61' | La Liga | 20 Sept 2025 |
| Antonio Sivera | Alavés | vs Villarreal | 58' | La Liga | 8 Mar 2025 |
| Antonio Blanco | Alavés | vs Villarreal | 90' | La Liga | 8 Mar 2025 |
| Óscar Mingueza | Celta Vigo | vs Athletic Club | 90' | La Liga | 19 Jan 2025 |
| Juan Latasa | Real Valladolid | vs Valencia | 78' | La Liga | 13 Dec 2024 |
| Mikel Jauregizar | Athletic Club | vs Las Palmas | 56' | La Liga | 15 Sept 2024 |
| Largie Ramazani | Almería | vs Villarreal | 87' | La Liga | 21 Apr 2024 |
| Pepe Reina | Villarreal | vs Mallorca | 62' | La Liga | 20 Jan 2024 |
| Iván Villar | Celta Vigo | vs Real Betis | 88' | La Liga | 3 Jan 2024 |
| Sergio Ramos | Sevilla | vs Real Sociedad | 88' | La Liga | 26 Nov 2023 |
| Jesús Navas | Sevilla | vs Real Sociedad | 88' | La Liga | 26 Nov 2023 |
| Omar Mascarell | Mallorca | vs Real Betis | 45' | La Liga | 4 Nov 2023 |
| Alejandro Catena | Osasuna | vs Barcelona | 84' | La Liga | 3 Sept 2023 |
| Dani Vivian | Athletic Club | vs Real Betis | 90' | La Liga | 4 May 2023 |
| Hugo Mallo | Celta Vigo | vs Mallorca | 90' | La Liga | 17 Apr 2023 |
| Reiner | Girona | vs Espanyol | 71' | La Liga | 1 Apr 2023 |
| Sergi Gómez | Espanyol | vs Girona | 83' | La Liga | 1 Apr 2023 |
| Renato Tapia | Celta Vigo | vs Real Sociedad | 75' | La Liga | 18 Feb 2023 |
| Pedro Bigas | Elche | vs Celta Vigo | 90' | La Liga | 6 Jan 2023 |
| Edgar González | Real Betis | vs Valencia | 61' | La Liga | 10 Nov 2022 |
| Unai García | Osasuna | vs Valencia | 69' | La Liga | 7 Oct 2022 |
| Mouctar Diakhaby | Valencia | vs Osasuna | 90' | La Liga | 7 Oct 2022 |
| Rubén Peña | Osasuna | vs Valencia | 90' | La Liga | 7 Oct 2022 |
| Yaison Murillo | Celta Vigo | vs Barcelona | 58' | La Liga | 10 May 2022 |