| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Juankar | Real Zaragoza | vs Sevilla | 90' | La Liga | 27 Nov 2011 |
| Alberto Lopo | Getafe | vs Atlético Madrid | 28' | La Liga | 6 Nov 2011 |
| Jordi Amat | Espanyol | vs Levante | 57' | La Liga | 25 Sept 2011 |
| Walter Pandiani | Espanyol | vs Levante | 81' | La Liga | 25 Sept 2011 |
| Nelson Haedo Valdez | Hercules | vs Racing Santander | 61' | La Liga | 7 May 2011 |
| Laure | Deportivo La Coruña | vs Málaga | 45' | La Liga | 10 Apr 2011 |
| Manuel Gaspar Haro | Málaga | vs Real Madrid | 67' | La Liga | 3 Mar 2011 |
| David Albelda | Valencia | vs Real Madrid | 65' | La Liga | 4 Dec 2010 |
| Leonardo Ponzio | Real Zaragoza | vs Barcelona | 47' | La Liga | 23 Oct 2010 |
| Javier Camuñas | Osasuna | vs Deportivo La Coruña | 35' | La Liga | 17 Oct 2010 |