| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Íñigo López | Granada | vs Rayo Vallecano | 90' | La Liga | 14 Jan 2012 |
| Eliseu | Málaga | vs Rayo Vallecano | 36' | La Liga | 26 Oct 2011 |
| Mario | Real Betis | vs Athletic Club | 75' | La Liga | 18 Sept 2011 |
| Fernando Amorebieta | Athletic Club | vs Real Betis | 90' | La Liga | 18 Sept 2011 |
| Ricardo Carvalho | Real Madrid | vs Real Zaragoza | 86' | La Liga | 30 Apr 2011 |
| Andrés Palop | Sevilla | vs Deportivo La Coruña | 57' | La Liga | 29 Jan 2011 |
| Antonio López | Atlético Madrid | vs Mallorca | 69' | La Liga | 17 Jan 2011 |
| Jonathan de Guzmán | Mallorca | vs Atlético Madrid | 87' | La Liga | 17 Jan 2011 |
| Gerard Piqué | Barcelona | vs Getafe | 69' | La Liga | 7 Nov 2010 |
| Derek Boateng | Getafe | vs Barcelona | 80' | La Liga | 7 Nov 2010 |
| Jirí Jarosík | Real Zaragoza | vs Sporting Gijón | 47' | La Liga | 2 Oct 2010 |