| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Leonardo Daniel Ponzio | Real Zaragoza | vs Barcelona | 46' | La Liga | 23 Oct 2010 |
| César Palacios Chocarro | CD Numancia de Soria | vs Barcelona | 79' | La Liga | 24 Jan 2009 |
| Iriney Santos Da Silva | Celta Vigo | vs Barcelona | 86' | La Liga | 28 Aug 2006 |