| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Alexander Prudnikov | Rubin Kazan | vs Real Betis | 28' | UEFA Europa League | 20 Feb 2014 |
| Adil Rami | Valencia | vs Swansea City | 10' | UEFA Europa League | 19 Sept 2013 |
| Luís Neto | Zenit St Petersburg | vs FC Nordsjælland | 72' | UEFA Champions League | 7 Aug 2013 |
| Fernandes Domingos Willians | Udinese | vs Anzhi Makhachkala | 80' | UEFA Europa League | 22 Nov 2012 |
| Emiliano Insúa | Sporting CP | vs Lazio | 51' | UEFA Europa League | 29 Sept 2011 |
| Gary Medel | Sevilla | vs Hannover 96 | 89' | UEFA Europa League | 25 Aug 2011 |