| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Pape Gueye | Sevilla | vs Celta Vigo | 19' | La Liga | 7 Apr 2023 |
| Marcos Acuña | Sevilla | vs Celta Vigo | 90' | La Liga | 7 Apr 2023 |
| Yuri Berchiche | Athletic Club | vs Cádiz | 57' | La Liga | 3 Feb 2023 |
| Lucas Boyé | Elche | vs Mallorca | 61' | La Liga | 10 Oct 2022 |
| Vedat Muriqi | Mallorca | vs Elche | 85' | La Liga | 10 Oct 2022 |
| Marcos André | Valencia | vs Espanyol | 85' | La Liga | 2 Oct 2022 |
| Martin Braithwaite | Espanyol | vs Valencia | 90' | La Liga | 2 Oct 2022 |
| Yangel Herrera | Espanyol | vs Alavés | 46' | La Liga | 11 May 2022 |
| Mikel Vesga | Athletic Club | vs Cádiz | 71' | La Liga | 21 Apr 2022 |
| Germán | Granada | vs Levante | 54' | La Liga | 17 Apr 2022 |