| Player | Opponent | Min | Referee | Competition | Date |
|---|---|---|---|---|---|
| Welinton | vs Borussia Dortmund | 43' | – | UEFA Champions League | 7 Dec 2021 |
| Souza | vs Sporting CP | 90' | – | UEFA Champions League | 3 Nov 2021 |
| Jeremain Lens | vs Braga | 44' | – | UEFA Europa League | 7 Nov 2019 |
| Ricardo Quaresma | vs Malmö FF | 65' | – | UEFA Europa League | 13 Dec 2018 |
| Álvaro Negredo | vs LASK Linz | 90' | – | UEFA Europa League | 16 Aug 2018 |
| Domagoj Vida | vs Bayern Munich | 16' | – | UEFA Champions League | 20 Feb 2018 |
| Vincent Aboubakar | vs Olympiacos | 39' | – | UEFA Europa League | 16 Mar 2017 |
| Andreas Beck | vs Dynamo Kyiv | 29' | – | UEFA Champions League | 6 Dec 2016 |
| Vincent Aboubakar | vs Dynamo Kyiv | 56' | – | UEFA Champions League | 6 Dec 2016 |
| Olcay Sahan | vs Club Brugge | 90' | – | UEFA Europa League | 19 Mar 2015 |
| Atiba Hutchinson | vs Asteras Tripoli | 73' | – | UEFA Europa League | 27 Nov 2014 |
| Ricardo Quaresma | vs Dynamo Kyiv | 90' | Pedro Proenca | UEFA Europa League | 17 Feb 2011 |
| Ibrahim Toraman | vs FC Porto | 66' | Paolo Tagliavento | UEFA Europa League | 4 Nov 2010 |