| Player | Opponent | Min | Referee | Competition | Date |
|---|---|---|---|---|---|
| Enrique García | vs Getafe | 88' | – | La Liga | 22 Nov 2020 |
| Pape Diop | vs Real Valladolid | 73' | – | La Liga | 3 Oct 2020 |
| Pape Diop | vs Celta Vigo | 87' | – | La Liga | 12 Sept 2020 |
| Paulo Oliveira | vs Valencia | 90' | – | La Liga | 4 Jan 2020 |
| Fabián Orellana | vs Getafe | 90' | – | La Liga | 8 Dec 2019 |
| Gonzalo Escalante | vs Real Betis | 90' | – | La Liga | 4 Oct 2019 |
| Anaitz Arbilla | vs Real Valladolid | 72' | – | La Liga | 10 Nov 2018 |
| Pablo de Blasis | vs Alavés | 62' | – | La Liga | 4 Nov 2018 |
| Fabián Orellana | vs Barcelona | 66' | – | La Liga | 17 Feb 2018 |
| Charles | vs Alavés | 83' | – | La Liga | 25 Nov 2017 |
| Joan Jordán | vs Athletic Club | 90' | – | La Liga | 27 Aug 2017 |
| Ander Capa | vs Barcelona | 74' | – | La Liga | 21 May 2017 |
| Asier Riesgo | vs Alavés | 26' | – | La Liga | 27 Apr 2017 |
| Gonzalo Escalante | vs Athletic Club | 56' | – | La Liga | 24 Apr 2017 |
| Florian Lejeune | vs Real Sociedad | 46' | – | La Liga | 28 Feb 2017 |
| Yoel | vs Sevilla | 45' | – | La Liga | 17 Sept 2016 |
| Dani García | vs Sevilla | 86' | – | La Liga | 17 Sept 2016 |
| Asier Riesgo | vs Granada | 32' | – | La Liga | 11 Sept 2016 |
| Josip Radosevic | vs Rayo Vallecano | 85' | – | La Liga | 12 Mar 2016 |
| Lillo | vs Sevilla | 88' | – | La Liga | 2 Mar 2016 |
| Iván Ramis | vs Valencia | 90' | – | La Liga | 13 Dec 2015 |
| Keko | vs Villarreal | 76' | – | La Liga | 22 Nov 2015 |
| Raúl Navas | vs Rayo Vallecano | 90' | – | La Liga | 3 Apr 2015 |
| Dani García | vs Levante | 89' | – | La Liga | 6 Mar 2015 |
| Federico Piovaccari | vs Elche | 78' | – | La Liga | 16 Feb 2015 |
| Federico Piovaccari | vs Córdoba | 58' | – | La Liga | 16 Jan 2015 |
| Raúl Navas | vs Málaga | 88' | – | La Liga | 8 Nov 2014 |