| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Lucas Hernández | Atlético Madrid | vs Eibar | 63' | La Liga | 20 May 2018 |
| Eneko Satrustegui | Osasuna | vs Real Madrid | 54' | La Liga | 6 Nov 2011 |
| Medhi Lacen | Getafe | vs Málaga | 75' | La Liga | 1 Oct 2011 |
| Francisco Jesus Perez Malia | Racing Santander | vs Athletic Club | 73' | La Liga | 21 May 2011 |
| Toni | Real Zaragoza | vs Mallorca | 64' | La Liga | 19 Mar 2011 |
| Leonardo Ulloa | Almería | vs Málaga | 76' | La Liga | 28 Feb 2011 |
| Antonio Luna | Almería | vs Málaga | 88' | La Liga | 28 Feb 2011 |
| David Navarro | Valencia | vs Racing Santander | 53' | La Liga | 31 Jan 2011 |
| Ricardo Costa | Valencia | vs Racing Santander | 89' | La Liga | 31 Jan 2011 |
| Medhi Lacen | Racing Santander | vs Valencia | 90' | La Liga | 31 Jan 2011 |
| Abel Aguilar | Hercules | vs Getafe | 89' | La Liga | 3 Oct 2010 |
| Carlos Garcia | Almería | vs Osasuna | 90' | La Liga | 29 Aug 2010 |