| Player | Opponent | Min | Referee | Competition | Date |
|---|---|---|---|---|---|
| Francisco Jesus Perez Malia | vs Málaga | 3' | – | La Liga | 9 Apr 2012 |
| Pape Diop | vs Sevilla | 79' | – | La Liga | 22 Mar 2012 |
| Marcos Gullon | vs Espanyol | 52' | – | La Liga | 19 Mar 2012 |
| Toño | vs Rayo Vallecano | 3' | – | La Liga | 3 Mar 2012 |
| Domingo Cisma | vs Real Madrid | 39' | – | La Liga | 18 Feb 2012 |
| Pedro Munitis | vs Valencia | 90' | – | La Liga | 29 Jan 2012 |
| Pape Diop | vs Levante | 81' | Alberto Undiano Mallenco | La Liga | 11 Sept 2011 |
| Francisco Jesus Perez Malia | vs Athletic Club | 73' | Alfonso Alvarez Izquierdo | La Liga | 21 May 2011 |
| Henrique | vs Almería | 17' | Carlos Velasco Carballo | La Liga | 3 Mar 2011 |
| Christian Fernández | vs Sevilla | 39' | Eduardo Iturralde Gonzalez | La Liga | 12 Feb 2011 |
| Medhi Lacen | vs Valencia | 90' | Alfonso Alvarez Izquierdo | La Liga | 31 Jan 2011 |
| Pedro Munitis | vs Athletic Club | 90' | Rafael Ramirez Dominguez | La Liga | 15 Jan 2011 |
| Domingo Cisma | vs Levante | 27' | David Fernandez Borbalan | La Liga | 21 Nov 2010 |
| Markus Rosenberg | vs Getafe | 90' | Ignacio Iglesias Villanueva | La Liga | 26 Sept 2010 |
| Ebi Smolarek | vs Barcelona | 66' | César Muñiz | La Liga | 26 Aug 2007 |
| Antonio Rodríguez Martínez | vs Barcelona | 89' | Carlos Velasco Carballo | La Liga | 17 Sept 2006 |
| David Aganzo Méndez | vs Barcelona | 73' | Rafael Ramírez Domínguez | La Liga | 27 Nov 2005 |