| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Pedro Bigas | Mallorca | vs Racing Santander | 85' | La Liga | 27 Nov 2011 |
| Juan Forlín | Espanyol | vs Villarreal | 75' | La Liga | 6 Nov 2011 |
| Daniel Majstorovic | Celtic | vs FC Sion | 3' | UEFA Europa League | 25 Aug 2011 |
| Sergio | Osasuna | vs Atlético Madrid | 84' | La Liga | 3 Apr 2011 |
| José Ángel | Sporting Gijón | vs Villarreal | 65' | La Liga | 13 Mar 2011 |
| Rafael Sastre | Sporting Gijón | vs Villarreal | 90' | La Liga | 13 Mar 2011 |
| Diego Godín | Atlético Madrid | vs Valencia | 90' | La Liga | 12 Feb 2011 |
| Francisco Javier Farinós Zapata | Hércules | vs Barcelona | 84' | La Liga | 29 Jan 2011 |
| Cani | Villarreal | vs Real Madrid | 83' | La Liga | 9 Jan 2011 |
| Domingo Cisma | Racing Santander | vs Levante | 27' | La Liga | 21 Nov 2010 |
| Jon Aurtenetxe | Athletic Club | vs Villarreal | 76' | La Liga | 7 Nov 2010 |
| Tomáš Ujfaluši | Atlético Madrid | vs Barcelona | 92' | La Liga | 19 Sept 2010 |
| Rafael Márquez Álvarez | Barcelona | vs Racing Santander | 87' | La Liga | 1 Feb 2009 |
| Gerard Piqué Bernabéu | Barcelona | vs Racing Santander | 92' | La Liga | 1 Feb 2009 |
| Javier Casas Cuevas | Athletic Club | vs Barcelona | 18' | La Liga | 30 Sept 2006 |