| Player | Opponent | Min | Referee | Competition | Date |
|---|---|---|---|---|---|
| Jorge Meré | vs Celta Vigo | 74' | – | La Liga | 26 Feb 2017 |
| Diego Mariño | vs Leganés | 70' | – | La Liga | 12 Feb 2017 |
| Lillo | vs Málaga | 71' | – | La Liga | 4 Nov 2016 |
| Alberto Lora | vs Barcelona | 74' | – | La Liga | 24 Sept 2016 |
| Nacho Cases | vs Getafe | 56' | – | La Liga | 8 May 2016 |
| Ognjen Vranjes | vs Barcelona | 84' | – | La Liga | 23 Apr 2016 |
| Sergio Álvarez | vs Granada | 84' | – | La Liga | 3 Mar 2016 |
| Nacho Cases | vs Espanyol | 83' | – | La Liga | 27 Feb 2016 |
| Luis Hernández | vs Sevilla | 74' | – | La Liga | 12 Dec 2015 |
| Bernardo Espinosa | vs Rayo Vallecano | 39' | – | La Liga | 23 Sept 2015 |
| Roberto Canella | vs Real Madrid | 79' | – | La Liga | 14 Apr 2012 |
| Alberto Lora | vs Real Betis | 43' | Javier Estrada Fernandez | La Liga | 8 Jan 2012 |
| Carmelo González | vs Real Betis | 90' | Javier Estrada Fernandez | La Liga | 8 Jan 2012 |
| Sebastián Eguren | vs Real Madrid | 80' | Eduardo Iturralde Gonzalez | La Liga | 3 Dec 2011 |
| Alberto Lora | vs Real Sociedad | 90' | Jose Luis Paradas Romero | La Liga | 27 Aug 2011 |
| José Ángel | vs Villarreal | 65' | David Fernandez Borbalan | La Liga | 13 Mar 2011 |
| Rafael Sastre | vs Villarreal | 90' | David Fernandez Borbalan | La Liga | 13 Mar 2011 |
| Alberto Lora | vs Getafe | 85' | Jose Antonio Teixeira Vitienes | La Liga | 6 Mar 2011 |
| Sebastián Eguren | vs Sevilla | 26' | Antonio Rubinos Perez | La Liga | 1 Mar 2011 |
| Grégory | vs Athletic Club | 16' | Jose Antonio Teixeira Vitienes | La Liga | 5 Feb 2011 |
| Alberto Botía | vs Real Madrid | 90' | Javier Turienzo Alvarez | La Liga | 14 Nov 2010 |
| Gerard Autet Serrabasa | vs Barcelona | 56' | Carlos Megía Dávila | La Liga | 21 Sept 2008 |