| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Gerard Autet Serrabasa | Sporting Gijón | vs Barcelona | 56' | La Liga | 21 Sept 2008 |
| Rafael Márquez Álvarez | Barcelona | vs Athletic Club | 76' | La Liga | 2 Sept 2007 |
| Koikili Lertxundi Del Campo | Athletic Club | vs Barcelona | 79' | La Liga | 2 Sept 2007 |
| Eduardo Nicolás Tuzzio | Mallorca | vs Barcelona | 72' | La Liga | 29 Jan 2006 |
| Delio Cesar Toledo | Real Zaragoza | vs Barcelona | 75' | La Liga | 1 Oct 2005 |