| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Alberto Lora | Sporting Gijón | vs Real Betis | 43' | La Liga | 8 Jan 2012 |
| Carmelo González | Sporting Gijón | vs Real Betis | 90' | La Liga | 8 Jan 2012 |
| Iván Marcano | Getafe | vs Racing Santander | 87' | La Liga | 20 Feb 2011 |
| Marius Stankevicius | Valencia | vs Villarreal | 81' | La Liga | 20 Nov 2010 |
| Rafa | Getafe | vs Málaga | 61' | La Liga | 23 Sept 2010 |
| Jesús Gámez | Málaga | vs Getafe | 66' | La Liga | 23 Sept 2010 |
| Jose Carlos de Araujo Nunes | Mallorca | vs Sporting Gijón | 84' | La Liga | 12 Sept 2010 |