| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Michael Jakobsen | Almería | vs Sevilla | 52' | La Liga | 1 May 2011 |
| Sebastián Eguren | Sporting Gijón | vs Sevilla | 26' | La Liga | 1 Mar 2011 |
| Martín Demichelis | Málaga | vs Valencia | 15' | La Liga | 22 Jan 2011 |
| Helder Miguel do Rosario | Málaga | vs Valencia | 65' | La Liga | 22 Jan 2011 |
| Matías Fritzler | Hercules | vs Athletic Club | 90' | La Liga | 28 Aug 2010 |
| José Edmílson Gomes de Moraes | Barcelona | vs Mallorca | 91' | La Liga | 11 May 2008 |