| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Abdelaziz Barrada | Getafe | vs Sporting Gijón | 62' | La Liga | 20 Nov 2011 |
| Sami Khedira | Real Madrid | vs Levante | 40' | La Liga | 18 Sept 2011 |
| Alberto Lopo | Deportivo La Coruña | vs Atlético Madrid | 59' | La Liga | 30 Apr 2011 |
| Ikechukwu Uche | Real Zaragoza | vs Villarreal | 90' | La Liga | 18 Apr 2011 |
| Damiá | Osasuna | vs Real Sociedad | 90' | La Liga | 13 Feb 2011 |
| Alberto Botía | Sporting Gijón | vs Real Madrid | 90' | La Liga | 14 Nov 2010 |
| Abdoulay Konko | Sevilla | vs Barcelona | 45' | La Liga | 30 Oct 2010 |