| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Sebastián Eguren | Sporting Gijón | vs Real Madrid | 80' | La Liga | 3 Dec 2011 |
| Álvaro Cejudo | Osasuna | vs Levante | 59' | La Liga | 30 Oct 2011 |
| Bruno Alves | Zenit St Petersburg | vs Apoel Nicosia | 76' | UEFA Champions League | 13 Sept 2011 |
| Christian Fernández | Racing Santander | vs Sevilla | 39' | La Liga | 12 Feb 2011 |
| Sergio Ramos | Real Madrid | vs Barcelona | 90' | La Liga | 29 Nov 2010 |
| Sergio Ramos García | Real Madrid | vs Barcelona | 91' | La Liga | 29 Nov 2010 |
| Javier Chica | Espanyol | vs Villarreal | 85' | La Liga | 12 Sept 2010 |
| David Albelda Aliqués | Valencia | vs Barcelona | 60' | La Liga | 18 Feb 2007 |
| Anderson Luís de Souza | Barcelona | vs Valencia | 61' | La Liga | 18 Feb 2007 |
| Thiago Motta | Barcelona | vs Real Zaragoza | 71' | La Liga | 12 Nov 2006 |
| Gabriel Alejandro Milito | Real Zaragoza | vs Barcelona | 75' | La Liga | 12 Nov 2006 |