| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Fernando Amorebieta | Athletic Club | vs Barcelona | 90' | La Liga | 6 Nov 2011 |
| Adil Rami | Valencia | vs Mallorca | 90' | La Liga | 15 Oct 2011 |
| Ángel Di María | Real Madrid | vs Rayo Vallecano | 56' | La Liga | 24 Sept 2011 |
| Javi López | Espanyol | vs Real Zaragoza | 85' | La Liga | 18 Sept 2011 |
| Carlos Martínez | Real Sociedad | vs Sporting Gijón | 68' | La Liga | 27 Aug 2011 |
| Alberto Lora | Sporting Gijón | vs Real Sociedad | 90' | La Liga | 27 Aug 2011 |
| Xabier Castillo | Athletic Club | vs Osasuna | 57' | La Liga | 17 Apr 2011 |
| Sergio | Osasuna | vs Athletic Club | 87' | La Liga | 17 Apr 2011 |
| Pablo Álvarez | Deportivo La Coruña | vs Espanyol | 42' | La Liga | 13 Mar 2011 |
| Cata Díaz | Getafe | vs Villarreal | 41' | La Liga | 11 Dec 2010 |
| Juan Albín | Getafe | vs Villarreal | 90' | La Liga | 11 Dec 2010 |
| Juan Calatayud | Hercules | vs Espanyol | 79' | La Liga | 21 Nov 2010 |