| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Gorka Elustondo | Real Sociedad | vs Villarreal | 62' | La Liga | 11 Dec 2011 |
| Pape Diop | Racing Santander | vs Levante | 81' | La Liga | 11 Sept 2011 |
| Matías Fritzler | Hercules | vs Málaga | 66' | La Liga | 1 May 2011 |
| Carlos Marchena | Villarreal | vs Sevilla | 85' | La Liga | 24 Apr 2011 |
| Cristan Pulhac | Hercules | vs Getafe | 90' | La Liga | 27 Feb 2011 |
| Álvaro Arbeloa | Real Madrid | vs Getafe | 82' | La Liga | 3 Jan 2011 |
| Nico Gaitan | Benfica | vs Lyon | 43' | UEFA Champions League | 20 Oct 2010 |
| Miroslav Klose | Germany | vs Serbia | 37' | 2010 FIFA World Cup | 18 Jun 2010 |
| Abdoulay Konko | Sevilla | vs Barcelona | 55' | La Liga | 8 May 2010 |
| Daniel Alves da Silva | Barcelona | vs Espanyol | 61' | La Liga | 17 Apr 2010 |
| Sergio Busquets i Burgos | Barcelona | vs Real Madrid | 61' | La Liga | 29 Nov 2009 |
| Lassana Diarra | Real Madrid | vs Barcelona | 89' | La Liga | 29 Nov 2009 |
| Luís Fabiano Clemente | Sevilla | vs Barcelona | 84' | La Liga | 29 Nov 2008 |
| Oleguer Presas Renom | Barcelona | vs Real Madrid | 44' | La Liga | 10 Mar 2007 |