| Player | Opponent | Min | Referee | Competition | Date |
|---|---|---|---|---|---|
| Jérôme Boateng | vs Sweden | 82' | Szymon Marciniak | 2018 FIFA World Cup | 23 Jun 2018 |
| Miroslav Klose | vs Serbia | 37' | Alberto Undiano Mallenco | 2010 FIFA World Cup | 18 Jun 2010 |
| Carsten Ramelow | vs Cameroon | 40' | Antonio López Nieto | 2002 FIFA World Cup | 11 Jun 2002 |
| Christian Wörns | vs Croatia | 40' | Rune Pedersen | 1998 FIFA World Cup | 4 Jul 1998 |