| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Iñigo Martínez | Real Sociedad | vs Racing Santander | 54' | La Liga | 18 Dec 2011 |
| Jérémy Toulalan | Málaga | vs Villarreal | 75' | La Liga | 28 Nov 2011 |
| Emilio Nsue | Mallorca | vs Osasuna | 72' | La Liga | 1 Oct 2011 |
| Jordi Alba | Valencia | vs Barcelona | 90' | La Liga | 21 Sept 2011 |
| Henrique | Racing Santander | vs Almería | 17' | La Liga | 3 Mar 2011 |
| Matteo Contini | Real Zaragoza | vs Villarreal | 64' | La Liga | 27 Nov 2010 |
| Koikili Lertxundi Del Campo | Athletic Club | vs Almería | 45' | La Liga | 13 Nov 2010 |
| Xabier Castillo | Athletic Club | vs Almería | 69' | La Liga | 13 Nov 2010 |
| Xisco Nadal | Levante | vs Espanyol | 56' | La Liga | 24 Oct 2010 |
| Antonio Rodríguez Martínez | Racing Santander | vs Barcelona | 89' | La Liga | 17 Sept 2006 |