| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Raúl Albiol i Tortajada | Real Madrid | vs Barcelona | 50' | La Liga | 16 Apr 2011 |
| Matías Gustavo Alustiza | Xerez | vs Barcelona | 89' | La Liga | 24 Apr 2010 |
| Fabián Ariel Orellana Valenzuela | Xerez | vs Barcelona | 92' | La Liga | 24 Apr 2010 |
| Hedwiges Maduro | Valencia | vs Barcelona | 68' | La Liga | 14 Mar 2010 |
| Ebi Smolarek | Racing Santander | vs Barcelona | 66' | La Liga | 26 Aug 2007 |
| Fabiano Eler dos Santos | Atlético Madrid | vs Barcelona | 71' | La Liga | 20 May 2007 |
| Rafael Márquez Álvarez | Barcelona | vs Villarreal | 87' | La Liga | 4 Dec 2005 |