| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Sito Riera | Chornomorets | vs PSV Eindhoven | 87' | UEFA Europa League | 12 Dec 2013 |
| Jonas | Valencia | vs Real Sociedad | 41' | La Liga | 1 Dec 2012 |
| Jaba Kankava | Dnipro Dnipropetrovsk | vs PSV Eindhoven | 84' | UEFA Europa League | 22 Nov 2012 |
| Mubarak Wakaso | Espanyol | vs Real Betis | 66' | La Liga | 22 Sept 2012 |
| Jorge Lourenco | AEL | vs Partizan Belgrade | 28' | UEFA Champions League | 8 Aug 2012 |
| Pepe | Real Madrid | vs Sevilla | 44' | La Liga | 17 Dec 2011 |
| Manu | Sevilla | vs Real Madrid | 74' | La Liga | 17 Dec 2011 |
| Pedro Botelho | Rayo Vallecano | vs Levante | 77' | La Liga | 21 Sept 2011 |
| Monolas Kostas | AEK Athens | vs Anderlecht | 78' | UEFA Europa League | 15 Sept 2011 |
| Fernando Soriano | Osasuna | vs Racing Santander | 75' | La Liga | 13 Mar 2011 |
| Ricardo Carvalho | Real Madrid | vs Sevilla | 63' | La Liga | 19 Dec 2010 |
| Mouhamadou Dabo | Sevilla | vs Real Madrid | 90' | La Liga | 19 Dec 2010 |
| Fernando Navarro | Sevilla | vs Athletic Club | 64' | La Liga | 24 Oct 2010 |
| Maicon | FC Porto | vs Besiktas | 44' | UEFA Europa League | 21 Oct 2010 |
| Fernando | FC Porto | vs Besiktas | 88' | UEFA Europa League | 21 Oct 2010 |
| Eliseu | Málaga | vs Almería | 41' | La Liga | 3 Oct 2010 |
| Pepe | Real Madrid | vs Espanyol | 60' | La Liga | 21 Sept 2010 |
| Ernesto Galán | Espanyol | vs Real Madrid | 62' | La Liga | 21 Sept 2010 |
| Juan Forlín | Espanyol | vs Real Madrid | 88' | La Liga | 21 Sept 2010 |
| Zlatan Ibrahimović | Barcelona | vs Almería | 59' | La Liga | 6 Mar 2010 |
| Gerard Piqué Bernabéu | Barcelona | vs Villarreal | 73' | La Liga | 21 Dec 2008 |