| Player | Opponent | Min | Referee | Competition | Date |
|---|---|---|---|---|---|
| Jan Bednarek | vs Nottingham Forest | 8' | Danny Makkelie | UEFA Europa League | 16 Apr 2026 |
| Stephen Eustáquio | vs AS Roma | 51' | Francois Letexier | UEFA Europa League | 20 Feb 2025 |
| Pepê | vs Internazionale | 90' | Szymon Marciniak | UEFA Champions League | 14 Mar 2023 |
| Otávio | vs Internazionale | 78' | Srdjan Jovanovic | UEFA Champions League | 22 Feb 2023 |
| Mehdi Taremi | vs Atlético Madrid | 81' | Szymon Marciniak | UEFA Champions League | 7 Sept 2022 |
| Wendell | vs Atlético Madrid | 71' | – | UEFA Champions League | 7 Dec 2021 |
| Agustín Marchesín | vs Atlético Madrid | 75' | – | UEFA Champions League | 7 Dec 2021 |
| Chancel Mbemba | vs Atlético Madrid | 90' | – | UEFA Champions League | 15 Sept 2021 |
| Mehdi Taremi | vs Juventus | 54' | – | UEFA Champions League | 9 Mar 2021 |
| Marko Grujic | vs Marseille | 67' | – | UEFA Champions League | 25 Nov 2020 |
| Tiquinho Soares | vs Bayer Leverkusen | 85' | – | UEFA Europa League | 27 Feb 2020 |
| Felipe | vs AS Monaco | 38' | – | UEFA Champions League | 6 Dec 2017 |
| Maxi Pereira | vs Juventus | 40' | – | UEFA Champions League | 14 Mar 2017 |
| Alex Telles | vs Juventus | 27' | – | UEFA Champions League | 22 Feb 2017 |
| Iván Marcano | vs Bayern Munich | 87' | – | UEFA Champions League | 21 Apr 2015 |
| Fernando | vs Sevilla | 87' | Wolfgang Stark | UEFA Europa League | 3 Apr 2014 |
| Héctor Herrera | vs Zenit St Petersburg | 6' | – | UEFA Champions League | 22 Oct 2013 |
| Steven Defour | vs Málaga | 49' | – | UEFA Champions League | 13 Mar 2013 |
| Rolando | vs Manchester City | 77' | Wolfgang Stark | UEFA Europa League | 22 Feb 2012 |
| Jorge Fucile | vs Zenit St Petersburg | 45' | Howard Webb | UEFA Champions League | 28 Sept 2011 |
| Álvaro Pereira | vs Sevilla | 72' | Howard Webb | UEFA Europa League | 23 Feb 2011 |
| Cristian Rodríguez | vs Besiktas | 60' | Paolo Tagliavento | UEFA Europa League | 4 Nov 2010 |
| Maicon | vs Besiktas | 44' | Carlos Clos Gomez | UEFA Europa League | 21 Oct 2010 |
| Fernando | vs Besiktas | 88' | Carlos Clos Gomez | UEFA Europa League | 21 Oct 2010 |