| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Gonzalo Rodríguez | Fiorentina | vs Juventus | 69' | UEFA Europa League | 20 Mar 2014 |
| Andy Carroll | West Ham United | vs Swansea City | 59' | Premier League | 1 Feb 2014 |
| Tom Huddlestone | Hull City | vs Norwich City | 89' | Premier League | 18 Jan 2014 |
| Ante Rukavina | Dinamo Zagreb | vs Austria Vienna | 71' | UEFA Champions League | 21 Aug 2013 |
| Per Mertesacker | Arsenal | vs West Bromwich Albion | 70' | Premier League | 6 Apr 2013 |
| Emmanuel Adebayor | Tottenham Hotspur | vs Arsenal | 18' | Premier League | 17 Nov 2012 |
| Dusan Matovic | Hapoel Kiryat Shmona | vs BATE Borisov | 70' | UEFA Champions League | 22 Aug 2012 |
| Jorge Fucile | FC Porto | vs Zenit St Petersburg | 45' | UEFA Champions League | 28 Sept 2011 |
| Ivan Klasnic | Bolton Wanderers | vs Norwich City | 45' | Premier League | 17 Sept 2011 |
| Carl Jenkinson | Arsenal | vs Manchester United | 77' | Premier League | 28 Aug 2011 |
| Phil Bardsley | Sunderland | vs Newcastle United | 89' | Premier League | 20 Aug 2011 |
| Philippe Mexes | AS Roma | vs Shakhtar Donetsk | 41' | UEFA Champions League | 8 Mar 2011 |
| Álvaro Pereira | FC Porto | vs Sevilla | 72' | UEFA Europa League | 23 Feb 2011 |
| Alexis | Sevilla | vs FC Porto | 77' | UEFA Europa League | 23 Feb 2011 |
| Jean Makoun | Aston Villa | vs Blackpool | 70' | Premier League | 12 Feb 2011 |
| Fabricio Coloccini | Newcastle United | vs Bolton Wanderers | 76' | Premier League | 20 Nov 2010 |
| John Heitinga | Netherlands | vs Spain | 109' | 2010 FIFA World Cup | 11 Jul 2010 |