| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Carlos Soler | Real Sociedad | vs Barcelona | 88' | La Liga | 18 Jan 2026 |
| Federico Viñas | Real Oviedo | vs Alavés | 75' | La Liga | 4 Jan 2026 |
| Carlos Protesoni | Alavés | vs Real Oviedo | 88' | La Liga | 4 Jan 2026 |
| Robert Andrich | Bayer Leverkusen | vs Paris Saint-Germain | 33' | UEFA Champions League | 21 Oct 2025 |
| Illia Zabarnyi | Paris Saint-Germain | vs Bayer Leverkusen | 37' | UEFA Champions League | 21 Oct 2025 |
| Sergio Camello | Rayo Vallecano | vs Sevilla | 90' | La Liga | 28 Sept 2025 |
| Dean Huijsen | Real Madrid | vs Real Sociedad | 32' | La Liga | 13 Sept 2025 |
| José Gayà | Valencia | vs Osasuna | 22' | La Liga | 24 Aug 2025 |
| Igor Zubeldia | Real Sociedad | vs Real Betis | 20' | La Liga | 16 Feb 2025 |
| Sheraldo Becker | Real Sociedad | vs Real Betis | 75' | La Liga | 16 Feb 2025 |
| Dário Essugo | Las Palmas | vs Osasuna | 72' | La Liga | 24 Jan 2025 |
| Juan Berrocal | Getafe | vs Celta Vigo | 65' | La Liga | 4 Nov 2024 |
| Pepelu | Valencia | vs Las Palmas | 69' | La Liga | 21 Oct 2024 |
| Pape Gueye | Villarreal | vs Valencia | 68' | La Liga | 31 Aug 2024 |
| Yeray | Athletic Club | vs Getafe | 58' | La Liga | 3 May 2024 |
| Aitor Paredes | Athletic Club | vs Getafe | 79' | La Liga | 3 May 2024 |
| Jude Bellingham | Real Madrid | vs Valencia | 90' | La Liga | 2 Mar 2024 |
| Víctor Chust | Cádiz | vs Celta Vigo | 33' | La Liga | 4 Dec 2023 |
| Juan Miranda | Real Betis | vs Sevilla | 87' | La Liga | 21 May 2023 |
| Nicolas Jackson | Villarreal | vs Real Sociedad | 90' | La Liga | 2 Apr 2023 |
| Ángel Correa | Atlético Madrid | vs Real Madrid | 64' | La Liga | 25 Feb 2023 |
| Ronael Pierre-Gabriel | Espanyol | vs Osasuna | 45' | La Liga | 4 Feb 2023 |
| Abde Ezzalzouli | Osasuna | vs Espanyol | 45' | La Liga | 4 Feb 2023 |
| Robert Lewandowski | Barcelona | vs Osasuna | 30' | La Liga | 8 Nov 2022 |
| Gerard Piqué | Barcelona | vs Osasuna | 45' | La Liga | 8 Nov 2022 |
| Ander Herrera | Athletic Club | vs Sevilla | 90' | La Liga | 8 Oct 2022 |
| Aaron Cresswell | West Ham United | vs Eintracht Frankfurt | 19' | UEFA Europa League | 5 May 2022 |