| Player | Opponent | Min | Referee | Competition | Date |
|---|---|---|---|---|---|
| Dário Essugo | vs Real Betis | 61' | José María Sánchez Martínez | La Liga | 9 Mar 2025 |
| Scott McKenna | vs Real Valladolid | 29' | Ricardo de Burgos Bengoetxea | La Liga | 28 Feb 2025 |
| Dário Essugo | vs Osasuna | 72' | Jesús Gil Manzano | La Liga | 24 Jan 2025 |
| Benito Ramírez | vs Real Madrid | 64' | Alejandro Quintero González | La Liga | 19 Jan 2025 |
| Saúl Coco | vs Sevilla | 6' | Alejandro Muñiz Ruiz | La Liga | 14 Apr 2024 |
| Álvaro Valles | vs Barcelona | 24' | Mateo Busquets Ferrer | La Liga | 30 Mar 2024 |
| Aarón Escandell | vs Granada | 71' | Mateo Busquets Ferrer | La Liga | 3 Feb 2024 |
| Daley Sinkgraven | vs Barcelona | 90' | Pablo González Fuertes | La Liga | 4 Jan 2024 |
| Mika Mármol | vs Granada | 58' | Ricardo de Burgos Bengoetxea | La Liga | 24 Sept 2023 |
| Míchel Macedo | vs Real Betis | 86' | – | La Liga | 19 Apr 2018 |
| Alejandro Gálvez | vs Villarreal | 90' | – | La Liga | 11 Mar 2018 |
| Alen Halilovic | vs Valencia | 33' | – | La Liga | 18 Aug 2017 |
| Hernán | vs Deportivo La Coruña | 79' | – | La Liga | 20 May 2017 |
| Kevin-Prince Boateng | vs Atlético Madrid | 65' | – | La Liga | 29 Apr 2017 |
| Marko Livaja | vs Alavés | 86' | – | La Liga | 23 Apr 2017 |
| Aythami Artiles | vs Deportivo La Coruña | 77' | – | La Liga | 20 Jan 2017 |
| Kevin-Prince Boateng | vs Real Sociedad | 21' | – | La Liga | 21 Sept 2016 |
| Pedro Bigas | vs Sevilla | 88' | – | La Liga | 10 Sept 2016 |
| Aythami Artiles | vs Real Betis | 41' | – | La Liga | 19 Apr 2016 |
| Aythami Artiles | vs Sporting Gijón | 71' | – | La Liga | 6 Dec 2015 |
| Emmanuel Culio | vs Getafe | 80' | – | La Liga | 18 Oct 2015 |
| Javi Varas | vs Celta Vigo | 11' | – | La Liga | 13 Sept 2015 |