| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Charles Pickel | Espanyol | vs Mallorca | 54' | La Liga | 15 Mar 2026 |
| Jhon Durán | Fenerbahce | vs Ferencvaros | 90' | UEFA Europa League | 27 Nov 2025 |
| Luka Ilic | Real Oviedo | vs Valencia | 90' | La Liga | 30 Sept 2025 |
| Christantus Uche | Getafe | vs Espanyol | 60' | La Liga | 18 Apr 2025 |
| Scott McKenna | Las Palmas | vs Real Valladolid | 29' | La Liga | 28 Feb 2025 |
| Antonio Raíllo | Mallorca | vs Celta Vigo | 78' | La Liga | 6 Dec 2024 |
| Toni Lato | Mallorca | vs Villarreal | 69' | La Liga | 14 Sept 2024 |
| Giorgi Mamardashvili | Valencia | vs Barcelona | 45' | La Liga | 29 Apr 2024 |
| Pep Chavarría | Rayo Vallecano | vs Girona | 76' | La Liga | 26 Feb 2024 |
| Djené | Getafe | vs Cádiz | 44' | La Liga | 6 Nov 2023 |
| Mika Mármol | Las Palmas | vs Granada | 58' | La Liga | 24 Sept 2023 |
| Germán Pezzella | Real Betis | vs Getafe | 78' | La Liga | 24 May 2023 |
| Vinícius Júnior | Real Madrid | vs Valencia | 90' | La Liga | 21 May 2023 |
| Florian Lejeune | Rayo Vallecano | vs Atlético Madrid | 62' | La Liga | 9 Apr 2023 |
| Selim Amallah | Real Valladolid | vs Celta Vigo | 84' | La Liga | 26 Feb 2023 |
| Edson Álvarez | Ajax Amsterdam | vs 1. FC Union Berlin | 90' | UEFA Europa League | 23 Feb 2023 |
| William Carvalho | Real Betis | vs Barcelona | 90' | La Liga | 1 Feb 2023 |
| José Ángel Carmona | Sevilla | vs Celta Vigo | 86' | La Liga | 30 Dec 2022 |
| Álex Baena | Villarreal | vs Almería | 56' | La Liga | 23 Oct 2022 |
| Manu Morlanes | Villarreal | vs Almería | 58' | La Liga | 23 Oct 2022 |
| Nahuel Molina | Atlético Madrid | vs Villarreal | 90' | La Liga | 21 Aug 2022 |