| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Óscar Valentín | Rayo Vallecano | vs Mallorca | 80' | La Liga | 11 Jan 2026 |
| Tochi Phil Chukwuani | SK Sturm Graz | vs Celtic | 70' | UEFA Europa League | 23 Oct 2025 |
| Carl Starfelt | Celta Vigo | vs Real Sociedad | 45' | La Liga | 19 Oct 2025 |
| Domingos Duarte | Getafe | vs Celta Vigo | 90' | La Liga | 24 May 2025 |
| Pablo Barrios | Atlético Madrid | vs Celta Vigo | 7' | La Liga | 15 Feb 2025 |
| Juan Soriano | Leganés | vs Espanyol | 90' | La Liga | 11 Jan 2025 |
| Samú Costa | Mallorca | vs Athletic Club | 23' | La Liga | 28 Oct 2024 |
| Alfonso González | Celta Vigo | vs Osasuna | 86' | La Liga | 1 Sept 2024 |
| Vitor Roque | Barcelona | vs Alavés | 72' | La Liga | 3 Feb 2024 |
| Darwin Machis | Cádiz | vs Girona | 10' | La Liga | 7 Oct 2023 |
| Chimy Ávila | Osasuna | vs Atlético Madrid | 85' | La Liga | 28 Sept 2023 |
| Álvaro Morata | Atlético Madrid | vs Osasuna | 85' | La Liga | 28 Sept 2023 |
| Martin Hongla | Real Valladolid | vs Cádiz | 80' | La Liga | 19 May 2023 |
| Mikel Merino | Real Sociedad | vs Mallorca | 90' | La Liga | 12 Mar 2023 |
| Germán Pezzella | Real Betis | vs Osasuna | 73' | La Liga | 26 Aug 2022 |
| Iván Balliu | Rayo Vallecano | vs Alavés | 88' | La Liga | 16 Apr 2022 |