| Player | Opponent | Min | Referee | Competition | Date |
|---|---|---|---|---|---|
| Seydouba Cissé | vs Girona | 19' | José Luis Munuera Montero | La Liga | 24 Apr 2025 |
| Munir El Haddadi | vs Alavés | 90' | Pablo González Fuertes | La Liga | 15 Feb 2025 |
| Sergio González | vs Rayo Vallecano | 45' | Alejandro Quintero González | La Liga | 31 Jan 2025 |
| Juan Soriano | vs Espanyol | 90' | Juan Martínez Munuera | La Liga | 11 Jan 2025 |
| Óscar Rodríguez | vs Villarreal | 58' | Alejandro Muñiz Ruiz | La Liga | 22 Dec 2024 |
| Jorge | vs Villarreal | 77' | Alejandro Muñiz Ruiz | La Liga | 22 Dec 2024 |
| Iván Cuéllar | vs Atlético Madrid | 90' | – | La Liga | 26 Jan 2020 |
| Kévin Rodrigues | vs Real Sociedad | 90' | – | La Liga | 8 Nov 2019 |
| Óscar Rodríguez | vs Osasuna | 90' | – | La Liga | 17 Aug 2019 |
| Unai Bustinza | vs Espanyol | 45' | – | La Liga | 12 May 2019 |
| Allan Nyom | vs Rayo Vallecano | 58' | – | La Liga | 4 Feb 2019 |
| Gerard Gumbau | vs Espanyol | 90' | – | La Liga | 4 Jan 2019 |
| Rubén Pérez | vs Getafe | 90' | – | La Liga | 7 Dec 2018 |
| Diego Rico | vs Real Betis | 23' | – | La Liga | 19 May 2018 |
| Joseba Zaldúa | vs Levante | 57' | – | La Liga | 7 May 2018 |
| Gabriel | vs Real Madrid | 90' | – | La Liga | 28 Apr 2018 |
| Dimitrios Siovas | vs Eibar | 84' | – | La Liga | 10 Feb 2018 |
| Nordin Amrabat | vs Levante | 68' | – | La Liga | 19 Dec 2017 |
| Alberto | vs Valencia | 80' | – | La Liga | 28 Feb 2017 |
| Iago Herrerín | vs Eibar | 26' | – | La Liga | 18 Dec 2016 |
| David Timor | vs Celta Vigo | 90' | – | La Liga | 22 Aug 2016 |