| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Costinha | Portugal | vs Netherlands | 45' | 2006 FIFA World Cup | 25 Jun 2006 |
| Khalid Boulahrouz | Netherlands | vs Portugal | 64' | 2006 FIFA World Cup | 25 Jun 2006 |
| Deco | Portugal | vs Netherlands | 78' | 2006 FIFA World Cup | 25 Jun 2006 |
| Giovanni van Bronckhorst | Netherlands | vs Portugal | 90' | 2006 FIFA World Cup | 25 Jun 2006 |