| Player | Opponent | Min | Referee | Competition | Date |
|---|---|---|---|---|---|
| Pepe | vs Germany | 37' | Milorad Mažić | 2014 FIFA World Cup | 16 Jun 2014 |
| Ricardo Costa | vs Spain | 89' | Héctor Baldassi | 2010 FIFA World Cup | 29 Jun 2010 |
| Costinha | vs Netherlands | 45' | Valentin Ivanov | 2006 FIFA World Cup | 25 Jun 2006 |
| Deco | vs Netherlands | 78' | Valentin Ivanov | 2006 FIFA World Cup | 25 Jun 2006 |
| João Pinto | vs South Korea | 27' | Ángel Sánchez | 2002 FIFA World Cup | 14 Jun 2002 |
| Beto | vs South Korea | 66' | Ángel Sánchez | 2002 FIFA World Cup | 14 Jun 2002 |