| Player | Opponent | Min | Referee | Competition | Date |
|---|---|---|---|---|---|
| Felipe Melo | vs Netherlands | 73' | Yuichi Nishimura | 2010 FIFA World Cup | 2 Jul 2010 |
| Kaká | vs Ivory Coast | 88' | Stéphane Lannoy | 2010 FIFA World Cup | 20 Jun 2010 |
| Ronaldinho | vs England | 57' | Felipe Ramos Rizo | 2002 FIFA World Cup | 21 Jun 2002 |
| Leonardo Araújo | vs United States | 43' | Joël Quiniou | 1994 FIFA World Cup | 4 Jul 1994 |
| Ricardo Gomes | vs Argentina | 85' | Joël Quiniou | 1990 FIFA World Cup | 24 Jun 1990 |
| Ricardo Gomes Raymundo | vs Argentina | 82' | Joël Quiniou | 1990 FIFA World Cup | 24 Jun 1990 |