| Player | Team | Opponent | Min | Competition | Date |
|---|---|---|---|---|---|
| Leonardo Araújo | Brazil | vs United States | 43' | 1994 FIFA World Cup | 4 Jul 1994 |
| Fernando Clavijo | United States | vs Brazil | 85' | 1994 FIFA World Cup | 4 Jul 1994 |
| Sergei Gorlukovich | Russia | vs Sweden | 49' | 1994 FIFA World Cup | 24 Jun 1994 |
| Ricardo Gomes | Brazil | vs Argentina | 85' | 1990 FIFA World Cup | 24 Jun 1990 |
| Ricardo Gomes Raymundo | Brazil | vs Argentina | 82' | 1990 FIFA World Cup | 24 Jun 1990 |